Creating more efficient lighting solutions and solar panels requires materials that let light pass through and conduct "missing electrons," or the charged holes created when an electron leaves. Scientists created just such a material by altering a transparent insulating oxide by chemical substitution. Even though conducting missing electrons and transparency were considered mutually exclusive, this new material both efficiently conducts missing electrons and retains most of its transparency to visual light.
This new material could lead to more efficient solar cells, light-emitting diodes, light detectors, and other transparent electronics.
Numerous applications from flat panel displays to solar cells require high-performance transparent conducting oxides. Commercial applications mainly use transparent oxides that conduct electrons. Their counterparts, transparent oxides that conduct "missing electrons" called holes, have not been commercialized due to their low conductivity. Conductivity and transparency were considered to be typically mutually exclusive properties. Now researchers at the Pacific Northwest National Laboratory (Washington State) along with collaborators at Binghamton University (New York) and the Paul Drude Institute (Berlin) have made a new material that conducts holes, while maintaining much of its transparency. The new material with a special perovskite structure efficiently conducts holes and maintains most of its transparency. The material is made by chemically substituting strontium for up to 25 percent of the lanthanum in lanthanum chromium oxide. To demonstrate the potential of this new material, crystalline films were grown on strontium titanate by a process called molecular beam epitaxy. When light was absorbed in this two-layered film, electrons and holes were generated. The electrons moved into the strontium titanate layer, while the holes moved into the new material. This new transparent film has "hole-conductivity" that is competitive with the best known hole-conducting transparent oxides. Based on its structural and chemical compatibility, this new material offers great promise for integration into and enhanced performance of electronics based only on perovskite oxides. These oxide electronics require positively charged and negatively charged materials to be put in contact with each other. With this new material, both layers can have compatible structures called perovskites. Examples of oxide electronics include high-power devices and sensors.
Pacific Northwest National Laboratory
This work was supported by the DOE Office of Science (Office of Basic Energy Sciences) and the Environmental Molecular Sciences Laboratory and the National Synchrotron Light Source, DOE Office of Science User Facilities; Pacific Northwest National Laboratory (computational aspects); National Science Foundation (Binghamton University); and National Institute of Standards and Technology (Beamline X24a).
K. Zhang, Y. Du, A. Papadogianni, O. Bierwagen, S. Sallis, L. Piper, M. Bowden, V. Shutthanandan, P. Sushko, and S. Chambers, "Perovskite Sr-doped LaCrO3 as a new p-type transparent conducting oxide." Advanced Materials 27, 5191 (2015). [DOI: 10.1002/adma.201501959].