Squeezed Quantum Dots Produce More Stable Light

March 1, 2019

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Squeezed Quantum Dots Produce More Stable Light
Novel colloidal quantum dots are formed from an emitting cadmium selenium (CdSe) core (red) enclosed into a shell (green) where the fraction of zinc (Zn) versus cadmium (Cd) increases toward the dot's periphery. The core is compressed (lines) more strongly perpendicular to the crystal axis than along it. This leads to modifications of the core's electronic structure, which beneficially affects its light-emission properties.

The Science

Tiny light sources could advance sensors, quantum communication, bioimaging, and medical diagnostic tools. To develop these nano light bulbs, researchers are looking to quantum dots, little bits of semiconducting materials. One problem with "standard" quantum dots, though, is that the emitted light isn't stable. Researchers have made progress in finding ways to reduce blinking in light emission intensity but other aspects of light emission such a color still fluctuate. In this study, by squeezing the emitting core during synthesis, researchers created dots that emit extraordinarily stable light that's well suited for scientific needs.

The Impact

This study points to the potential of a new method of quantum dot synthesis. Essentially, by squeezing, this method creates quantum dots that produce highly stable light. Also, this method could offer flexible modification and control of light-emitting properties. The strained dots represent a viable alternative to today's nanoscale light sources. The dots could lead to advances in single particle nanoscale light sources for use in optical quantum circuits, ultra-high-resolution sensors, and medical nanomarkers.

Summary

Modern synthesis techniques produce nearly ideal quantum-dot light emitters, which are used in quantum-dot displays and TV sets. But what if a single quantum dot could be a light source? These tiny light bulbs could benefit optical quantum circuits, ultrasensitive sensors, bioimaging tools, and medical diagnostics. To create such single-particle light sources, researchers need highly stable quantum dots that don't blink and have stable and controllable emission color. A team based at Los Alamos National Laboratory did just that. They devised a way to create quantum dots that don't blink with stable emission spectra by "squeezing" the emitting core of the dot during synthesis. Their strain-engineering approach modifies the structures of electronic states of a quantum dot and, thereby, its light-emitting properties. The resulting dots emit steady light and have a dramatic narrowing of the emission linewidth, which becomes smaller than the room-temperature thermal energy. The spectral stability achieved is comparable to that of tiny light emitters made via sophisticated, vacuum-based techniques. This suggests that colloidal quantum dots synthesized through strain engineering represent a viable alternative to presently employed nanoscale light sources. In addition to exhibiting comparable (or even improved) performance, these dots could offer unprecedented flexibility in manipulating their emission color combined with compatibility with virtually any substrate or embedding medium as well as various chemical and biological environments.

Contact

Victor I. Klimov
Los Alamos National Laboratory
klimov@lanl.gov   

Funding

The Solar Photochemistry Program of the Chemical Sciences, Biosciences, and Geosciences Division, Office of Basic Energy Sciences, Office of Science, Department of Energy (V.I.K. and Y.S.P.) and the Laboratory Directed Research and Development Program at Los Alamos National Laboratory (J.L.).   

Publications

Y.S. Park, J. Lim, and V.I. Klimov, "Asymmetrically strained quantum dots with non-fluctuating single-dot emission spectra and subthermal room-temperature linewidths." Nature Materials (2019). [DOI: 10.1038/s41563-018-0254-7]

Related Links

Los Alamos National Laboratory press release: More stable light comes from intentionally "squashed" quantum dotsExternal link   

Highlight Categories

Program: BES, CSGB

Performer/Facility: University, DOE Laboratory