In cage-structured compounds, the atoms surround a large open space that can be filled with other atoms or molecules, making these materials very useful in nature and for technologies. In nature, the atoms in these compounds (called clathrates) are always bonded to four other atoms. The bonds define the open volume in the cage. For the first time ever, scientists synthesized cage-structured compounds with each atom bonded to five, six, or more atoms—making the cage larger, tunable, and more technologically interesting.
The larger cages let atoms move freely, limiting how heat flows. Lower thermal conductivity makes clathrates promising to harvest waste heat and turn it into electricity. This discovery opens the door to develop new clathrate materials. These materials could enhance our understanding of the connection between a material's structure and behavior.
Cage-like metallic compounds called clathrates have the potential to be used as thermoelectric materials for harvesting waste heat and turning it into electricity, due to their tendency to exhibit both high electrical conductivity and low thermal conductivity. Chemists working at the University of California, Davis have discovered a whole new class of clathrates, potentially opening new ways to make and apply these materials. A clathrate is a framework compound with guest atoms trapped inside—held in oversized cage structures. Because the cage is relatively large compared to the guest atom, the trapped atom can rattle around, and that means that clathrates conduct heat very poorly, a necessary characteristic of thermoelectric materials. Thermoelectrics convert heat into electricity and could potentially be used for applications from powering a watch with body heat to making vehicles more efficient by recovering waste heat from the exhaust. To date, all known clathrates have been based on a tetrahedral structure: each atom in the cage is bonded with four other atoms. Now, more than 200 years after the original clathrates were discovered, the University of California, Davis team has produced and characterized stable clathrates with atoms having five, six or more bonds. These groundbreaking materials offer the potential for new insights into the fundamental structure-property relationships of clathrates, and opportunities to create improved thermoelectrics or other functional materials.
University of California, Davis
U.S. Department of Energy, Office of Science, Basic Energy Sciences; user facilities involved: Advanced Photon Source and Spallation Neutron Source, both U.S. Department of Energy Office of Science scientific user facilities
J.A. Dolyniuk, J.V. Zaikina, D.C. Kaseman, S. Sen, and K. Kovnir, "Breaking the tetra-coordinated framework rule: New clathrate Ba8M24P28+?(M=Cu/Zn)." Angewandte Chemie International Edition 56, 2418 (2017). [DOI: 10.1002/anie.201611510]?
Inside Back Cover: "Breaking the tetra-coordinated framework rule: New clathrate Ba8M24P28+? (M=Cu/Zn)." Angewandte Chemie International Edition 56, 2513 (2017). [DOI: 10.1002/anie.201700221]
F. Baumer, and T. Nilges, "Highlight: Inorganic clathrates: A polyhedron with 22 vertices and up to ninefold coordinated phosphorus atoms." Angewandte Chemie International Edition 56, 3424 (2017). [DOI: 10.1002/anie.201700835]